Why there are differences in the activation energy between maximum analysis and direct analysis?
The calculation of the time constants (shown in the Arrhenius plot) are completely different to each other. It should be the same for a pure exponential transient. It should be similar if the data class of the direct analysis is better than 60. Only for a class higher than 60 a direct analysis is realy valid. The standard should be the maximum analysis with two period widths. An Arrhenius plot with only one constant period widths file is only for an estimated energy and can implement a great error.
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