Why lithium compounds behave similarly with magnesium compounds but not with other alkali metal compounds?
They are not that dissimilar from the rest of Gp 1 compounds, but do have some similarities with magnesium compounds because of the similar charge/size ratios of the lithium and magnesium ions. This ‘diagonal relationship’ happens to a greater or lesser extent with quite a few pairs of elements in similar positions. Be/Al, B/Si, C/P.