What is the best insulating ceramic thermal conductor?
The best insulating (electrical) ceramic thermal conductive material is beryllium oxide (BeO). The material is an electric insulator yet conducts heat at the alarming rate of 280 W/mK (on average at room temperature). The next best is Al-N followed by Si and Al-O. BeO is versatile, easily metallized and can be used for many applications. There are some safety issues associated with BeO but when coated and placed in a package the concerns are greatly diminished.