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What are the windows of the cockpit made out of and why don they melt or shatter during re-entry?

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What are the windows of the cockpit made out of and why don they melt or shatter during re-entry?

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ANSWER from Kurt Bush on October 31, 1997: Each shuttle window consists of three layers. The innermost pane is constructed of tempered aluminosilicate glass to withstand the crew compartment pressure. It is 0.625 of an inch thick. The exterior of this pane, called a pressure pane, is coated with a red reflector coating to reflect the infrared (heat portion) rays while transmitting the visible spectrum. The center pane is constructed of low-expansion, fused silica glass because of its high optical quality and excellent thermal shock resistance. This pane is 1.3 inches thick. The outer pane is made of the same material as the center pane and is 0.625 of an inch thick. The exterior is uncoated, but the interior is coated with high-efficiency, anti-reflection coating. The outer surface withstands approximately 800 F. The inner and outer panes are coated with a high-efficiency, anti-reflection coating to improve visible light transmission. These windows withstand a proof pressure of 8,600 p

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