Is chlorine dioxide effective over a wide pH range?
Because chlorine dioxide is a dissolved gas, it does not ionise to form weak acids (as chlorine and bromine do) in aqueous solutions. This allows chlorine dioxide to be effective over a wide pH range (5 – 10). For example, the pH dependent speciation of chlorine produces hypochlorite ion and hypochlorous acid (HOCl). Hypochlorite is only 1/30 to 1/200 as effective as HOCl. Chlorine dioxide being a neutral species with rapid disinfection kinetics is 100% available for disinfection in hard or soft water.