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I found that after calibrating the company’s trace oxygen analyzer on air (209,000 ppm O2), the accuracy of the readings at 75 ppm were way off. Why is this?

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I found that after calibrating the company’s trace oxygen analyzer on air (209,000 ppm O2), the accuracy of the readings at 75 ppm were way off. Why is this?

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Though checking a trace oxygen analyzer’s calibration on air may seem expedient, good calibration techniques suggest using a calibration gas with an oxygen concentration within the range of the analyzer. Calibrating on 209,000 ppm of oxygen and then expecting high precision readings at concentrations < 1,000 ppm is precarious.

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