How efficiently Do three pointlike particles sample phase space?
We show that the continuous phase space of a hard particle system can be mapped onto a discrete but infinite phase space. For three pointlike particles confined to a ring, the evolution of the system maps onto a chaotic walk on a hexagonal lattice. This facilitates direct measurement of the departure of the system from its original configuration. In special cases of mass ratios the phase space becomes closed and finite (nonergodic). There are qualitative differences between this chaotic walk and a random walk, in particular a more rapid sampling of phase space.
Related Questions
- Best practices for sample collection and preparation do not yet exist. Could a major portion of the first phase be devoted to the development of sample collection and preparation protocols?
- Sample diluent and mobile phase should be close in composition to provide good peak shape in RP systems. Is it still true for mixed mode separation?
- Do SPMDs sample only dissolved or vapor phase chemicals?