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How does the structure of capillaries allow them to transport the substances through the blood?

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How does the structure of capillaries allow them to transport the substances through the blood?

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Capillaries are very thin and therefore allow the substances to be diffused out of the thin layer of vein/artery. They are also very small and allow for a smaller amount of blood cells to be transported at one which helps to slow them down (also they are further away from heart) and deposit their substances to each cell.

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