How do liquids contaminate groundwater?
Some hazardous substances dissolve very slowly in water. When these substances seep into groundwater faster than they can dissolve, some of the contaminants will stay in liquid form. If the liquid is less dense than water, it will float on top of the water table, like oil on water. Pollutants in this form are called light non-aqueous phase liquids (LNAPLs). If the liquid is more dense than water, the pollutants are called dense non-aqueous phase liquids (DNAPLs). DNAPLs sink to form pools at the bottom of an aquifer. These pools continue to contaminate the aquifer as they slowly dissolve and are carried away by moving groundwater. As DNAPLs flow downward through an aquifer, tiny globs of liquid become trapped in the spaces between soil particles. This form of groundwater contamination is called residual contamination.