Does Pauli repulsion induce the dissociation energy barriers?
We elucidate the origin of the formation analyzing the dissociation process of oxygen molecule on bridge-top-bridge site of Pt(111). The charge state is analyzed by the Bader method together with the spin states of the two oxygen atoms. The charge transfers to the dissociated oxygen molecule from the Au surface. The potential energy variation is in agreement with the energy variation of the separated in distance, charged, and spin polarized oxygen molecules that is calculated with real- space density functional method. Excluding the exchange term in the total energy calculation of the H$_2$/Au system leads to a monotonic increase of the potential energy surface in the dissociation process. The energy barriers in the H$_2$/Mg, H$_2$/Pt, and H$_2$/Au systems are in agreement with the energy variations of the charged, isolated, and separated hydrogen molecules. The barriers appear in late dissociations although no barrier for the nondissociated adsorptions. Their electronegativity differe
