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Can I substitute bittersweet chocolate with unsweetened chocolate for a recipe?

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Can I substitute bittersweet chocolate with unsweetened chocolate for a recipe?

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Here’s a conversion – Chocolate, Semi-Sweet, 3 tablespoons chocolate chips = 1 square (1-ounce) unsweetened chocolate plus 1 tablespoon sugar or 1 square (1-ounce) semi-sweet chocolate; 6 tablespoons unsweetened cocoa powder plus 7 tablespoons sugar plus 1/4 cup fat can be substituted for 6 ounces semi-sweet chocolate.

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