Can CMake set the Debugging/Working Directory property in Visual Studio projects?
No. The value of this property is not stored in the project files. It is stored in extra files created by the IDE when a solution is loaded (VS .NET 2003 uses a hidden .suo file next to the .sln solution file). The format of these files is not known to CMake and cannot be generated. In some versions of VS the files are binary and not human readable.