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Can chocolate flavor substitute as coco powder?

chocolate Coco flavor powder
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Can chocolate flavor substitute as coco powder?

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You can substitute chocolate for cocoa. For every 3 tablespoons of cocoa called for in your recipe, substitute 1 ounce of unsweetened chocolate or 2 ounces of semisweet chocolate but cut the fat by 1 tablespoon and the sugar by 3 tablespoons.

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