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What does the -28 refer to in the MS-Product output?

MS output Product refer
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What does the -28 refer to in the MS-Product output?

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The -28 does refers to a difference of CO. The most commonly observed internal ions are of the ‘b’ ion type, but it is also possible to form an ‘a’ ion type internal ion through cleavage N-terminal to the carboxyl group.

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